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New Synthetic Routes to Polyoxometalate Containing Ionic Liquids

An Investigation of their Properties

  • Book
  • © 2015

Overview

Authors:
  1. Sven Herrmann

    1. Anorganische Chemie I, Universität Ulm, Ulm, Germany

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  • Publication in the field of natural sciences
  • Includes supplementary material: sn.pub/extras

Part of the book series: BestMasters (BEST)

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Table of contents (5 chapters)

  1. Front Matter

    Pages I-XXI
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  2. Introduction

    • Sven Herrmann
    Pages 1-17

  3. Objective

    • Sven Herrmann
    Pages 18-20

  4. Results and Discussion

    • Sven Herrmann
    Pages 21-92

  5. Summary and Perspective

    • Sven Herrmann
    Pages 93-96

  6. Experimental Section

    • Sven Herrmann
    Pages 97-118

  7. Back Matter

    Pages 119-122
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Keywords

About this book

In his Master project Sven Herrmann for the first time carried out fundamental investigations into the development of polyoxometalate based ionic liquids (POM-ILs). The POM-ILs were obtained by charge balancing inorganic polyoxometalate (POM) anions with sterically demanding tetraalkylammonium or tetraalkylphosphonium cations. By functionalization of lacunary Keggin clusters with 3d-transition metals and charge balancing with tetraalkylammonium cations of differing chain length, a model system for the correlation of the molecular structure with macroscopic materials properties was obtained. In a systematic approach the syntheses via self-aggregation is presented. Analytic methods comprise UV-Vis, FTIR, NMR, EPR and Mößbauer spectroscopy. For determination of the materials properties TGA and DSC were carried out and rheological studies shed light onto the flow characteristics of the highly viscous materials.

Authors and Affiliations

  • Anorganische Chemie I, Universität Ulm, Ulm, Germany

    Sven Herrmann

About the author

Sven Herrmann obtained his Masters degree at the University of Erlangen-Nürnberg. He then joined the working group of Prof. Carsten Streb in the inorganic department at the University of Ulm to work on his PhD thesis that targets the development of polyoxometalate based ionic liquids (POM-ILs).

Bibliographic Information

  • Book Title: New Synthetic Routes to Polyoxometalate Containing Ionic Liquids

  • Book Subtitle: An Investigation of their Properties

  • Authors: Sven Herrmann

  • Series Title: BestMasters

  • DOI: https://doi.org/10.1007/978-3-658-08796-8

  • Publisher: Springer Spektrum Wiesbaden

  • eBook Packages: Behavioral Science, Behavioral Science and Psychology (R0)

  • Copyright Information: Springer Fachmedien Wiesbaden 2015

  • Softcover ISBN: 978-3-658-08795-1Published: 11 March 2015

  • eBook ISBN: 978-3-658-08796-8Published: 11 February 2015

  • Series ISSN: 2625-3577

  • Series E-ISSN: 2625-3615

  • Edition Number: 1

  • Number of Pages: XXI, 122

  • Number of Illustrations: 61 b/w illustrations

  • Topics: Inorganic Chemistry, Catalysis, Industrial Chemistry/Chemical Engineering

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