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Keywords
- molecular structures in solutions
About this book
In the present thesis we develop new strategies concerning the use of lanthanide cations as spectroscopic probes for the study of molecular structures in solution. A widespread interest for lanthanides is mainly centered in two large fields: organic synthesis and clinical practice. Systems containing lanthanides enjoy a very favorable situation, since these ions feature high coordination numbers, which assure rich binding chemistry, and at the same time they possess the right spectroscopic properties to monitor it. The present thesis develops the potentialities of electronic spectroscopy of lanthanide systems in solution. We point out and overcome the drawbacks which have mainly hampered this kind of study so far, namely: a sensivity problem, an instrumental problem and a calibration problem.
Bibliographic Information
Book Title: NMR and NIR-CD studies on lanthanide complexes in solution
Authors: Guido Pintacuda
Series Title: Publications of the Scuola Normale Superiore
Publisher: Edizioni della Normale Pisa
Copyright Information: Edizioni della Normale 2004
Softcover ISBN: 978-88-7642-143-3Published: 01 October 2004
Series ISSN: 2239-1460
Series E-ISSN: 2532-1668
Edition Number: 1
Number of Pages: XII, 223