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  • © 1989

S Sulfur-Nitrogen Compounds

Compounds with Sulfur of Oxidation Number IV

Authors:

Editors:

  1. Hans-Jürgen Fachmann
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  2. Reimund Jotter
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  3. Alfons Kubny
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  4. Joachim Wagner
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  1. Norbert Baumann
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  2. Gerhard Czack
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  3. Brigitte Heibel
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  4. Peter Merlet
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  5. Joachim Wagner
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  6. Alfons Kubny
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Part of the book series: Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition (GMELIN, volume S / S-N / 5)

Part of the book sub series: S. Schwefel. Sulfur (System-Nr. 9) (2053)

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Table of contents (2 chapters)

  1. Front Matter

    Pages N1-XVI
    PDF

  2. Sulfur-Nitrogen Compounds with 1-Coordinate Sulfur

    • Hans-Jürgen Fachmann, Reimund Jotter, Alfons Kubny, Joachim Wagner, Norbert Baumann, Gerhard Czack et al.
    Pages 1-87

  3. Sulfur-Nitrogen Compounds with 2-Coordinate Sulfur

    • Hans-Jürgen Fachmann, Reimund Jotter, Alfons Kubny, Joachim Wagner, Norbert Baumann, Gerhard Czack et al.
    Pages 88-274

  4. Back Matter

    Pages 275-277
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About this book

The present volume is the first of a series describing acyclic sulfur-nitrogen compounds with sulfur of oxidation number IV. The acyclic sw-N compounds are arranged according to the coordination number of the sulfur. Neutral compounds are described before ions and complex compounds. The preceding series "Sulfur-Nitrogen Compounds" Parts 2, 3, and 4 covers the cyclic sw-N compounds. In this volume, the first section deals with sulfur-nitrogen compounds with 1-coordinate sulfur and begins with the sulfur nitride {thiazyl) radical, SN. This transient molecule was observed in its electronic ground state and several electronically excited states. The descrip­ tions of the sulfur nitride (thiazyl) ions SN+ and SW follow. The SN+ ionwas studied in the gas phase as weil as in the solid state where it forms salts. Thionitrosyl complexes containing the SN Iigand as a terminal linear unit are described at the end of the first section. The second section concerns Sulfur-nitrogen compounds with 2-coordinate sulfur and starts with the description of poly(sulfur nitride), (SNlx· The preparation, crystal structure, and metallic and superconducting properties of (SN)x, which were extensively studied, fill a !arge part of the volume. Halogen-modified poly(sulfur nitride) such as the widely studied (SNBr )x 04 and Na-modified poly(sulfur nitride) are dealt with in the following chapters.
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Keywords

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Bibliographic Information

  • Book Title: S Sulfur-Nitrogen Compounds

  • Book Subtitle: Compounds with Sulfur of Oxidation Number IV

  • Authors: Hans-Jürgen Fachmann, Reimund Jotter, Alfons Kubny, Joachim Wagner

  • Editors: Norbert Baumann, Gerhard Czack, Brigitte Heibel, Peter Merlet, Joachim Wagner, Alfons Kubny

  • Series Title: Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition

  • DOI: https://doi.org/10.1007/978-3-662-06357-6

  • Publisher: Springer Berlin, Heidelberg

  • eBook Packages: Springer Book Archive

  • Copyright Information: Springer-Verlag Berlin Heidelberg 1989

  • eBook ISBN: 978-3-662-06357-6Published: 11 November 2013

  • Edition Number: 8

  • Number of Pages: XVI, 276

  • Number of Illustrations: 57 b/w illustrations, 1 illustrations in colour

  • Topics: Chemistry/Food Science, general, Inorganic Chemistry

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eBook USD 74.99
Price excludes VAT (USA)
  • Available as PDF
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