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Lanthanides: Chemistry and Use in Organic Synthesis

  • Book
  • © 1999

Overview

Editors:
  1. Shū Kobayashi

    1. Graduate School of Pharmaceutical Sciences, The University of Tokyo, Tokyo, Japan

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  • Explains the principles of lanthanide chemistry, discusses unique reactivities and selectivities of rare earth elements, and reviews the major recent breakthroughs in their application to stereoselective organic synthesis and to catalytic processes including polymer synthesis and solid-phase catalysis *
  • A needed overview of recent advances by leading contributors in this field
  • Includes supplementary material: sn.pub/extras

Part of the book series: Topics in Organometallic Chemistry (TOPORGAN, volume 2)

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Table of contents (8 chapters)

  1. Front Matter

    Pages I-VII
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  2. Principles in Organolanthanide Chemistry

    • Reiner Anwander
    Pages 1-61

  3. Lanthanide Triflate-Catalyzed Carbon-Carbon Bond-Forming Reactions in Organic Synthesis

    • Shū Kobayashi
    Pages 63-118

  4. Lanthanide- and Group 3 Metallocene Catalysis in Small Molecule Synthesis

    • Gary A. Molander, Eric D. Dowdy
    Pages 119-154

  5. Influence of Solvents or Additives on the Organic Chemistry Mediated by Diiodosamarium

    • Henri B. Kagan, Jean-Louis Namy
    Pages 155-198

  6. Chiral Heterobimetallic Lanthanoid Complexes: Highly Efficient Multifunctional Catalysts for the Asymmetric Formation of C-C, C-O, and C-P Bonds

    • Masakatsu Shibasaki, Harald Gröger
    Pages 199-232

  7. Reactions of Ketones with Low-Valent Lanthanides: Isolation and Reactivity of Lanthanide Ketyl and Ketone Dianion Complexes

    • Zhaomin Hou, Yasuo Wakatsuki
    Pages 233-253

  8. Organo Rare Earth Metal Catalysis for the Living Polymerizations of Polar and Nonpolar Monomers

    • Hajime Yasuda
    Pages 255-283

  9. Polymer-Supported Rare Earth Catalysts Used in Organic Synthesis

    • Shū Kobayashi
    Pages 285-305

  10. Back Matter

    Pages 307-307
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Keywords

About this book

The use of lanthanides in organic chemistry and in organic synthesis has attracted broad interest recently because of the unique reactivities and selectivities exhibited by compounds of these rare earth elements. In particular, several major advances have been made in the last five years. This volume of Topics in Organometallic Chemistry is designed to provide the specialist and non-specialist alike with a much needed overview of recent developments. Contributions by leaders in the field focus on stereoselective organic synthesis using lanthanides, the principles of lanthanide chemistry, lanthanide-based chiral catalysts, low-valent lanthanide compounds, polymer synthesis using lanthanide catalysts, and polymer-supported lanthanide catalysts used in organic synthesis.

Editors and Affiliations

  • Graduate School of Pharmaceutical Sciences, The University of Tokyo, Tokyo, Japan

    Shū Kobayashi

Bibliographic Information

  • Book Title: Lanthanides: Chemistry and Use in Organic Synthesis

  • Editors: Shū Kobayashi

  • Series Title: Topics in Organometallic Chemistry

  • DOI: https://doi.org/10.1007/3-540-69801-9

  • Publisher: Springer Berlin, Heidelberg

  • eBook Packages: Springer Book Archive

  • Copyright Information: Springer-Verlag Berlin Heidelberg 1999

  • Hardcover ISBN: 978-3-540-64526-9Published: 08 March 1999

  • Softcover ISBN: 978-3-642-08419-5Published: 05 December 2010

  • eBook ISBN: 978-3-540-69801-2Published: 01 July 2003

  • Series ISSN: 1436-6002

  • Series E-ISSN: 1616-8534

  • Edition Number: 1

  • Number of Pages: IX, 307

  • Topics: Organic Chemistry, Inorganic Chemistry, Polymer Sciences

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