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Table of contents (11 chapters)
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Front Matter
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Back Matter
Keywords
About this book
The book provides an up-to-date review of the methods for synthesizing heteropoly oxometalates of Keggin structure, techniques from spectroscopic through electrochemical to elemental analysis for their characterization and the current information on their structure, bulk properties and their stabilities at high temperatures and under acid and alkaline conditions. The book discusses the materials employed as supports for the title solid and the results of the examination of the supported materials. Methods for the identification of the nature and source of the two catalytic functions, the acidic and oxidative properties, of the heteropoly oxometalates are reviewed and discussed. The use of both the supported and unsupported heteropoly oxometalates as catalysts in acidity-requisite processes ranging from methanol conversion to hydrocarbons to ring-expansion and contraction processes and in oxidation processes from methane cyclohexane are described and related to the aforementioned properties.
Reviews
Craig L. Hill in Journal of the American Chemical Society, 124:36 (2002)
Authors and Affiliations
Bibliographic Information
Book Title: Metal-Oxygen Clusters
Book Subtitle: The Surface and Catalytic Properties of Heteropoly Oxometalates
Authors: John B. Moffat
Series Title: Fundamental and Applied Catalysis
DOI: https://doi.org/10.1007/b115623
Publisher: Springer New York, NY
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eBook Packages: Springer Book Archive
Copyright Information: Springer Science+Business Media New York 2000
Hardcover ISBN: 978-0-306-46507-9Published: 30 June 2001
Softcover ISBN: 978-1-4757-7479-5Published: 23 March 2013
eBook ISBN: 978-0-306-47378-4Published: 11 December 2005
Series ISSN: 1574-0447
Edition Number: 1
Number of Pages: XV, 308
Topics: Catalysis, Inorganic Chemistry, Physical Chemistry, Industrial Chemistry/Chemical Engineering, Organic Chemistry