Novel Metathesis Chemistry: Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailored Polymers and Advanced Material Applications

1. Front Matter

   Pages i-xx

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2. The Alkene Metathesis Ruthenium Catalyst Saga

   • David Sémeril, Pierre H. Dixneuf

   Pages 1-21

3. Ruthenium Carbenes as Catalysts for Alkene Metathesis

   • Cédric Fischmeister, Ricardo Castarlenas, Christian Bruneau, Pierre H. Dixneuf

   Pages 23-42

4. Metathetical Conversion and Silylative Coupling of Alkadienes and Cycloalkenes with Mono- and Divinylsilicon Compounds

   • Bogdan Marciniec

   Pages 43-49

5. Synthesis of Organosilicon Reagents of Vinylsilicon Functionality via Cross-Metathesis and Silylation of Alkenes

   • Bogdan Marciniec

   Pages 51-64

6. Catalytic Properties and Chemical Transformations of CIS-W(CO)₄(C₅H₅N)₂ Initiator in Ring Opening Metathesis Polymerization

   • L. Bencze, L. Mihichuk

   Pages 65-71

7. The Impact of Well-Defined Transition Metal Initiators on ROMP

   • E. Khosravi

   Pages 73-85

8. Dual Activity of Ruthenium Catalysts in Controlled Radical Reactions and Olefin Metathesis

   • L. Delaude, S. Delfosse, A. Demonceau, A. Richel, A. F. Noels

   Pages 87-100

9. O,N- Bidentate Ligands Co-Ordinated on Ru-Based Olefin Metathesis Catalysts

   • B. D. Clercq, F. Verpoort

   Pages 101-119

10. Catalytic Activity of W-Sn and Mo-Sn Bimetallic Compounds in Metathesis and Related Reactions

    • T. Szymańska-Buzar

    Pages 121-129

11. Polymerizations Catalyzed with Rhodium Complexes

    • J. Vohlídal, M. Pacovská, J. Sedláček, J. Svoboda, J. Zedník, H. Balcar

    Pages 131-154

12. Mesoporous Molecular Sieves Immobilized Catalysts for Polymerization of Phenylacetylene and Its Derivatives

    • H. Balcar, J. Čejka, J. Sedláček, J. Svoboda, Z. Bastl, M. Pacovská et al.

    Pages 155-165

13. Study of the Stability and Activity of Electrochemically Produced Tungsten-Based Metathesis Catalyst with Symmetrical Alkenes

    • S. Çetinkaya, B. Düz, Y. Imamoğlu

    Pages 167-171

14. Immobilized Tungsten-Containing Catalysts for the Metathesis of Linear and Functionalized Olefins

    • O. V. Shouvalova, N. B. Bespalova, P. Nieczypor, J. C. Mol

    Pages 173-177

15. The Incorporation of Amino Acids into Polymers ADMET

    • Timothy E. Hopkins, Joshua M. Priebe, Kenneth B. Wagener

    Pages 179-189

16. Graft Copolymers Attained by ATRP and ADMET

    • Patrick M. O’Donnell, Kenneth B. Wagener

    Pages 191-202

17. Synthesis, Conformation, and Functions of Helical Poly(N-Propargylamides):

    • R. Nomura, J. Tabei, K. Yamada, T. Masuda

    Pages 203-213

18. Synthesis of Block Copolymers and Star Polymers through Living Polymerization of Substituted Acetylenes

    • K. Kanki, F. Sanda, T. Masuda

    Pages 215-227

19. Well-Defined Linear and Crosslinked Materials via ROMP and RTM Processing

    • E. Khosravi

    Pages 229-235

20. Ring Opening Metathesis Polymerisation (ROMP) of Cyclooctene and Substituted Norbornene Derivatives Using a Ruthenium Catalyst Containing a Triazol-5-Ylidene Ligand

    • Karen Melis, Dirk de Vos, Pierre Jacobs, Francis Verpoort

    Pages 237-242

A comprehensive discussion of the theory, practice and application of catalytically active transition metal species and their application in the production of specialist polymeric materials. The material is presented in a progressive manner, suitable for non-experts and those seeking an introduction to the field. The bibliographies supplied are complete and up to date, making the book an indispensable guide to the primary literature for the more theoretical background to the topics discussed.
After a comprehensive discussion of initiating systems for speciality chemical synthesis the book goes on to deal with a wide range of topics in materials science, including: alkenamers, polyacetylenes, industrial applications and liquid rocket engine fuels.

• Cadmium
• Cycloaddition
• ITIES
• Ion
• Ruthenium
• carbon
• catalyst
• chemical synthesis
• metals
• polymer
• rhodium
• silicon
• spectroscopy
• synthesis
• transition metal

• Department of Chemistry, Hacettepe University Beytepe, Ankara, Turkey

  Y. Imamoglu

• Department of Organic Chemistry, University of Veszprem, Veszprem, Hungary

  L. Bencze

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