Substituent Effects in Radical Chemistry

1. Front Matter

   Pages i-xiv

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2. A Theoretical Approach to Substituent Effects in Radical Chemistry

   • G. Leroy, D. Peeters, M. Sana, C. Wilante

   Pages 1-48

3. Sigma and PI Effects in Radicals

   • Timothy Clark

   Pages 49-68

4. The Contrasting Strain Energies of Small Ring Carbon and Silicon Rings. The Relationship with free Radical Energies

   • Paul Ragué von Schleyer

   Pages 69-81

5. Allylic and Allenic Capto-Dative Stabilization in Nitrogen Centered free Radicals

   • Daniel Kost, Morton Raban, Kalman Aviram

   Pages 83-86

6. Conformational Preferences in ß-Substituted Ethyl Radicals: A Quantitative Analysis of Hyperconjugation, Homoconjugation, d-Orbital and Steric Effects.

   • Jacques Fossey

   Pages 87-90

7. Substituent Effects on the Thermochemistry and Electrochemistry of Free Radicals

   • J. A. Hawari, J. M. Kanabus-Kaminska, D. D. M. Wayner, D. Griller

   Pages 91-105

8. Some Applications of ESR Spectroscopy to the Study of Substituent Effects

   • G. W. Burton, L. J. Johnston, J. C. Walton, K. U. Ingold

   Pages 107-122

9. Substituent Effects on Absolute Rate Constants and Arrhenius Parameters for the Addition of tert-Butyl Radicals to Alkenes

   • Hanns Fischer

   Pages 123-142

10. Allylic Radicals—An ESR Spectroscopical Study

    • Reiner Sustmann

    Pages 143-166

11. ESR-Spectroscopical Investigation of Capto-Dative Substituent Effects in Benzyl Radicals

    • H.-G. Korth, P. Lommes, R. Sustmann, L. Sylvander, L. Stella

    Pages 167-170

12. The Effect of Substituents on Benzylic Radical Esr Hyperfine Coupling Constants. The σ α • Scale Based Upon Spin Delocalization.

    • Donald R. Arnold

    Pages 171-188

13. Determination of Thermodynamic Stabilisation in Amino-Substituted Alkyl Radicals

    • Iain Maclnnes, John C. Walton, Derek C. Nonhebel

    Pages 189-190

14. Phosphinylhydrazyls \({{R}_{2}}N\dot{N}P\left( 0 \right){{L}_{2}}.\) Influence of the Phosphinyl Group on the 3-Electron NN π Bond

    • P. Tordo

    Pages 191-194

15. Substituent Effects on the Dimerization of Vinyl Nitroxides and on the Dissociation of Their Tricyclic Dimers

    • Hans Günter Aurich, Otto Bubenheim, Klaus-Dieter Mogendorf

    Pages 195-198

16. Substituent Effects on the CC-Bond Strength.

    • H. Birkhofer, H. D. Beckhaus, C. Rüchardt

    Pages 199-218

17. The Different Recombinations of Diphenyl Methyl Radicals Ph2 C.-R, R = tBu, CN, COOR’, COR’

    • W. P. Neumann, R. Stapel

    Pages 219-222

18. Some Chemistry of Radical Ions

    • J. M. Tedder

    Pages 223-244

19. Substituent Effects on the Methylenecyclopropane Rearrangement. A Probe for Free Radical Effects.

    • Xavier Creary

    Pages 245-262

20. 2-Oxomorpholin-3-YL Radicals

    • Tad H. Koch

    Pages 263-270

• Cycloaddition
• Hyperconjugation
• Nucleophilic substitution
• Rearrangement
• Steric effect

`This book as a top level scientific kaleidoscope is recommended to all organic chemists and related researchers who wish to know and apply the results of the modern radical chemistry. Anyone who would like to participate in the exciting further development of this area should read this book from cover to cover.'
Reaction Kinetics and Catalysis Letters, Vol. 34, No. 2, 1987

• University of Louvain, Louvain-la-Neuve, Belgium

  Heinz G. Viehe, Zdenek Janousek, Robert Merényi

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