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Chemistry - Theoretical and Computational Chemistry | Specific Intermolecular Interactions of Organic Compounds

Specific Intermolecular Interactions of Organic Compounds

Baev, Alexei K.

2012, XVIII, 434 p.

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  • Summarizes the recent progress in the field
  • The topic is crucial in many chemical and biochemical reactions
  • The topic is crucial in determining material properties
Prof. Baev presents in his book the development of the thermodynamic theory of specific intermolecular interactions for a wide spectrum of organic compounds: ethers, ketones, alcohols, carboxylic acids, and hydrocarbons. The fundamentals of an unconventional approach to the theory of H-bonding and specific interactions are formulated based on a concept of pentacoordinate carbon atoms. New types of hydrogen bonds and specific interactions are substantiated and on the basis of the developed methodology their energies are determined. The system of interconnected quantitative characteristics of the stability of specific intermolecular interactions is presented. The laws of their transformations are discussed and summarized. The new concept of the extra stabilizing effect of isomeric methyl groups on the structure and stability of organic molecules is introduced and the destabilization action on specific interactions is outlined.

Content Level » Research

Keywords » ethers - hydrocarbons - intermolecular interactions - organic compounds - organic cyclic oxides - sp3-hybridization model - theoretical organic chemistry - thermodynamics

Related subjects » Industrial Chemistry and Chemical Engineering - Organic Chemistry - Physical Chemistry - Theoretical and Computational Chemistry

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