Overview
- Nominated by Tohoku University as an outstanding Ph.D. thesis
- Novel experimental methods for structural analyses of very large water clusters are presented
- New chemical models for radiation-induced reactions in water are reported
- Includes supplementary material: sn.pub/extras
Part of the book series: Springer Theses (Springer Theses)
Access this book
Tax calculation will be finalised at checkout
Other ways to access
Table of contents (6 chapters)
Keywords
About this book
Authors and Affiliations
About the author
Kenta Mizuse, Ph.D.
Date of Birth: February 16, 1984
Place of Birth: Niigata, Japan
Nationality: Japan
Since April 2011
Department of Photo-Molecular Science (Prof. Yasuhiro Ohshima’s Lab.), Institute for Molecular Science, Japan
Assistant professor
April 2008-March 2011
The Japan Society for the Promotion of Science (JSPS) Research fellow
April 2006-March 2011
Department of Chemistry, Graduate School of Science, Tohoku University, Japan
Ph.D. student
Supervisor: Professor Asuka Fujii
Degree obtained: Ph.D. in Science
April 2002-March 2006
Department of Chemistry, Faculty of Science, Tohoku University, Japan
Undergraduate student
Supervisor: Professor Naohiko Mikami
Publications
1 Mizuse, K. & Fujii, A. Infrared Spectroscopy of Large Protonated Water Clusters H+(H2O)20-50 Cooled by Inert Gas Attachment. Chem. Phys. in press, doi:10.1016/j.chemphys.2012.07.012 (2013).
2 Mizuse, K. & Fujii, A. Tuning of the Internal Energy and Isomer Distribution in Small Protonated Water Clusters H+(H2O)4–8: An Application of the Inert Gas Messenger Technique. J. Phys. Chem. A 116, 4868-4877 (2012).
3 Mizuse, K., Suzuki, Y., Mikami, N. & Fujii, A. Solvation-Induced σ-Complex Structure Formation in the Gas Phase: A Revisit to the Infrared Spectroscopy of [C6H6–(CH3OH)2]+. J. Phys. Chem. A 115, 11156-11161 (2011).
4 Mizuse, K., Kuo, J.-L. & Fujii, A. Structural trends of ionized water networks: Infrared spectroscopy of water cluster radical cations(H2O)n+ (n = 3-11). Chem. Sci. 2, 868-876 (2011).
5 Mizuse, K. & Fujii, A. Structural Origin of the Antimagic Number in Protonated Water Clusters H+(H2O)n: Spectroscopic Observation of the “Missing” Water Molecule in the Outermost Hydration Shell. J. Phys. Chem. Lett. 2, 2130-2134 (2011).
6 Mizuse, K. & Fujii, A. Infrared photodissociation spectroscopy of H+(H2O)6·Mm (M = Ne, Ar, Kr, Xe, H2, N2, and CH4): messenger-dependent balance between H3O+ and H5O2+ core isomers. Phys. Chem. Chem. Phys. 13, 7129-7135 (2011).
7 Hamashima, T., Mizuse, K. & Fujii, A. Spectral Signatures of Four-Coordinated Sites in Water Clusters: Infrared Spectroscopy of Phenol−(H2O)n (~20 ≤ n ≤ ~50). J. Phys. Chem. A 115, 620-625 (2011).
8 Mizuse, K., Mikami, N. & Fujii, A. Infrared Spectra and Hydrogen-Bonded Network Structures of Large Protonated Water Clusters H+(H2O)n (n=20-200). Angew. Chem. Int. Ed. 49, 10119-10122 (2010).
9 Mizuse, K., Hasegawa, H., Mikami, N. & Fujii, A. Infrared and Electronic Spectroscopy of Benzene−Ammonia Cluster Radical Cations [C6H6(NH3)1,2]+: Observation of Isolated and Microsolvated σ-Complexes†. J. Phys. Chem. A 114, 11060-11069 (2010).
10 Mizuse, K., Hamashima, T. & Fujii, A. Infrared Spectroscopy of Phenol−(H2O)n>10: StructuralStrains in Hydrogen Bond Networks of Neutral Water Clusters. J. Phys. Chem. A 113, 12134-12141 (2009).
11 Hasegawa, H. et al. Observation of an isolated intermediate of the nucleophilic aromatic substition reaction by infrared spectroscopy. Angew. Chem. Int. Ed. 47, 6008-6010 (2008).
12 Suhara, K., Fujii, A., Mizuse, K., Mikami, N. & Kuo, J. L. Compatibility between methanol and water in the three-dimensional cage formation of large-sized protonated methanol-water mixed clusters. J. Chem. Phys. 126, 194306 (2007).
13 Mizuse, K., Fujii, A. & Mikami, N. Long range influence of an excess proton on the architecture of the hydrogen bond network in large-sized water clusters. J. Chem. Phys. 126, 231101 (2007).
14 Mizuse, K., Fujii, A. & Mikami, N. Infrared and electronic spectroscopy of a model system for the nucleophilic substitution intermediate in the gas phase: The C-N valence bond formation in the benzene-ammonia cluster cation. J. Phys. Chem. A 110, 6387-6390 (2006).
Bibliographic Information
Book Title: Spectroscopic Investigations of Hydrogen Bond Network Structures in Water Clusters
Authors: Kenta Mizuse
Series Title: Springer Theses
DOI: https://doi.org/10.1007/978-4-431-54312-1
Publisher: Springer Tokyo
eBook Packages: Chemistry and Materials Science, Chemistry and Material Science (R0)
Copyright Information: Springer Japan 2013
Hardcover ISBN: 978-4-431-54311-4Published: 22 January 2013
Softcover ISBN: 978-4-431-54683-2Published: 25 June 2015
eBook ISBN: 978-4-431-54312-1Published: 22 January 2013
Series ISSN: 2190-5053
Series E-ISSN: 2190-5061
Edition Number: 1
Number of Pages: XIII, 175
Topics: Physical Chemistry, Spectroscopy and Microscopy, Spectroscopy/Spectrometry