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Chemistry - Physical Chemistry | Visualization of Hydrogen-Bond Dynamics - Water-Based Model Systems on a Cu(110) Surface

Visualization of Hydrogen-Bond Dynamics

Water-Based Model Systems on a Cu(110) Surface

Series: Springer Theses, Vol. 125

Kumagai, Takashi

2012, XIV, 134 p.

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  • Addresses direct imaging of hydrogen-bond dynamics within water-based model systems assembled on a metal surface by a scanning tunneling microscope
  • Characterizes the dynamics of individual hydrogen bonds in small water clusters, hydroxyl clusters, and water-hydroxyl complexes at the single-molecule level
  • Was named best-in-department thesis (Chemistry, 2011) from the Graduate School of Science, Kyoto University
The hydrogen bond represents an important interaction between molecules, and the dynamics of hydrogen bonds in water create an ever-present question associated with the process of chemical and biological reactions. In spite of numerous studies, the process remains poorly understood at the microscopic level because hydrogen-bond dynamics, such as bond rearrangements and hydrogen/proton transfer reactions, are extremely difficult to probe. Those studies have been carried out by means of spectroscopic methods where the signal stems from the ensemble of a system and the hydrogen-bond dynamics were inferred indirectly. This book addresses the direct imaging of hydrogen-bond dynamics within water-based model systems assembled on a metal surface, using a scanning tunneling microscope (STM). The dynamics of individual hydrogen bonds in water clusters, hydroxyl clusters, and water-hydroxyl complexes are investigated in conjunction with density functional theory. In these model systems, quantum dynamics of hydrogen bonds, such as tunneling and zero-point nuclear motion, are observed in real space. Most notably, hydrogen atom relay reactions, which are frequently invoked across many fields of chemistry, are visualized and controlled by STM. This work presents a means of studying hydrogen-bond dynamics at the single-molecule level, providing an important contribution to wide fields beyond surface chemistry.

Content Level » Research

Keywords » Hydrogen Bond Dynamics - Hydrogen Transfer - Single Molecule Manipulation - Small Water Clusters - Vibrational Spectroscopy

Related subjects » Atomic, Molecular, Optical & Plasma Physics - Physical Chemistry

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