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Matrix Isolation Spectroscopy

  • Book
  • © 1981

Overview

Editors:
  1. A. J. Barnes

    1. Department of Chemistry, University of Salford, Salford, England

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  2. W. J. Orville-Thomas

    1. Department of Chemistry, University of Salford, Salford, England

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  3. A. Müller

    1. Universität Bielefeld, Bielefeld, West Germany

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  4. R. Gaufrès

    1. Laboratoire de Spectroscopie Moléculaire, U.S.T.L, Montpellier, France

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Part of the book series: Nato Science Series C: (ASIC, volume 76)

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Table of contents (24 chapters)

  1. Front Matter

    Pages i-x
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  2. The History of Matrix Isolation Spectroscopy

    1. The History of Matrix Isolation Spectroscopy

      • W. J. Orville-Thomas
      Pages 1-11

  3. Techniques

    1. Infrared and Raman Matrix Isolation Spectroscopy

      • A. J. Barnes
      Pages 13-26

    2. Electronic Spectroscopy of Matrix Isolated Solutes

      • Antony J Rest
      Pages 27-48

    3. Magnetic Circular Dichroism - Matrix Isolation Spectroscopy

      • R. Grinter
      Pages 49-68

    4. Electron Spin Resonance Studies of Radicals Trapped in Rare-Gas Matrices

      • Martyn C. R. Symons
      Pages 69-89

    5. Mössbauer Spectroscopy on Matrix — Isolated Species

      • H. Micklitz
      Pages 91-128

    6. Time and Frequency Resolved Vibrational Spectroscopy of Matrix Isolated Molecules: Population and Phase Relaxation Processes

      • H. Dubost
      Pages 129-171

    7. Stable Molecules

      • J. J. Turner
      Pages 173-186

    8. Generation and Trapping of Unstable Solutes in Low Temperature Matrices

      • Antony J Rest
      Pages 187-205

    9. The Characterisation of High Temperature Molecules Using Matrix Isolation and Vibrational Spectroscopy

      • J S Ogden
      Pages 207-230

    10. High Pressure Studies

      • Hai Vu
      Pages 231-263

    11. Non-Traditional Matrix Isolation: Adducts

      • J. J. Blaha, C. E. Meloan, W. G. Fateley
      Pages 265-273
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Keywords

About this book

The matrix isolation (MI) method has now been used for nearly thirty years. During this period it has been actively developed and the range of problems tackled greatly extended. Originally it was used for studies of transient species involv­ ing vibrational, electronic and ESR spectroscopy. Nowadays the study of transient species forms a comparatively small part of HI work since it has been amply demonstrated that very fruitful information can be obtained of the structure and interactions of stable molecules and their aggregates. In addition to the s~ectroscopic methods mentioned above the MI technique is nowadays a standard method in research based on vibrational relaxation, luminescence, Mossbauer, magnetic circular dichroism, pulsed NMR and photoelectron spectroscopy. The matrix isolation technique affords considerable advantages over more conventional methods in most applications of spectroscopy. Areas where the technique has been widely applied, or shows great potential, include: metal atom chemistry, and its relation to surface chemistry, high temperature inorganic species, transition metal complexes, interstellar species, free radicals and unstable molecules, conformational studies, molecular com­ plexes, and intermolecular forces.

Editors and Affiliations

  • Department of Chemistry, University of Salford, Salford, England

    A. J. Barnes, W. J. Orville-Thomas

  • Universität Bielefeld, Bielefeld, West Germany

    A. Müller

  • Laboratoire de Spectroscopie Moléculaire, U.S.T.L, Montpellier, France

    R. Gaufrès

Bibliographic Information

  • Book Title: Matrix Isolation Spectroscopy

  • Editors: A. J. Barnes, W. J. Orville-Thomas, A. Müller, R. Gaufrès

  • Series Title: Nato Science Series C:

  • DOI: https://doi.org/10.1007/978-94-009-8540-7

  • Publisher: Springer Dordrecht

  • eBook Packages: Springer Book Archive

  • Copyright Information: D. Reidel Publishing Company, Dordrecht, Holland 1981

  • Hardcover ISBN: 978-90-277-1328-5Published: 30 September 1981

  • Softcover ISBN: 978-94-009-8542-1Published: 12 October 2011

  • eBook ISBN: 978-94-009-8540-7Published: 06 December 2012

  • Series ISSN: 1389-2185

  • Edition Number: 1

  • Number of Pages: X, 605

  • Topics: Spectroscopy/Spectrometry, Spectroscopy and Microscopy

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