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Specific Intermolecular Interactions of Organic Compounds

  • Book
  • © 2012

Overview

Authors:
  1. Alexei K. Baev

    1. , Dept. of Chemistry, International Sakharov Environmental Uni, Minsk, Belarus

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  • Summarizes the recent progress in the field

  • The topic is crucial in many chemical and biochemical reactions

  • The topic is crucial in determining material properties

  • Includes supplementary material: sn.pub/extras

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Table of contents (8 chapters)

  1. Front Matter

    Pages i-xviii
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  2. Reverse Dative Bond in Organic Compounds, Molecular Complexes and Inconsistency of the sp 3-Hybridization Model with Respect to Carbon Atom

    • Alexei K. Baev
    Pages 1-28

  3. Nontraditional Approaches to Thermodynamic Analysis of Liquid Organic Compounds

    • Alexei K. Baev
    Pages 29-61

  4. Types and Energies of Specific Intermolecular Interactions in Ethers and Organic Cyclic Oxides

    • Alexei K. Baev
    Pages 63-130

  5. Specific Intermolecular Interactions of Ketones

    • Alexei K. Baev
    Pages 131-180

  6. Types and Energies of Hydrogen Bonds and Specific Intermolecular Interactions in Alcohols

    • Alexei K. Baev
    Pages 181-276

  7. Specific Intermolecular Interactions and H-bonds in Aldehydes and Esters

    • Alexei K. Baev
    Pages 277-324

  8. Types and Energies of Specific Intermolecular Interactions in Carboxylic Acids

    • Alexei K. Baev
    Pages 325-391

  9. Specific Intermolecular Interactions of Hydrocarbons

    • Alexei K. Baev
    Pages 393-430

  10. Back Matter

    Pages 431-434
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Keywords

About this book

Prof. Baev presents in his book the development of the thermodynamic theory of specific intermolecular interactions for a wide spectrum of organic compounds: ethers, ketones, alcohols, carboxylic acids, and hydrocarbons. The fundamentals of an unconventional approach to the theory of H-bonding and specific interactions are formulated based on a concept of pentacoordinate carbon atoms. New types of hydrogen bonds and specific interactions are substantiated and on the basis of the developed methodology their energies are determined. The system of interconnected quantitative characteristics of the stability of specific intermolecular interactions is presented. The laws of their transformations are discussed and summarized. The new concept of the extra stabilizing effect of isomeric methyl groups on the structure and stability of organic molecules is introduced and the destabilization action on specific interactions is outlined.

Authors and Affiliations

  • , Dept. of Chemistry, International Sakharov Environmental Uni, Minsk, Belarus

    Alexei K. Baev

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