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Activation of Unreactive Bonds and Organic Synthesis

  • Book
  • © 1999

Overview

Editors:
  1. Shinji Murai

    1. Department of Applied Chemistry Faculty of Engineering, Osaka University, Osaka

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  2. H. Alper
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  3. R. A. Gossage
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  4. V. V. Grushin
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  5. M. Hidai
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  6. Y. Ito
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  7. W. D. Jones
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  8. F. Kakiuchi
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  9. G. Koten
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  10. Y.-S. Lin
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  11. Y. Mizobe
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  12. S. Murai
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  13. M. Murakami
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  14. T. G. Richmond
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  15. A. Sen
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  16. M. Suginome
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  17. A. Yamamoto
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  • The first and only comprehensive overview of the explosive development in the field of bond activation, not only C-H but also other inert functionalities
  • Directed to organic and inorganic chemists
  • Presents new methodologies for bond cleavage and bond connection reactions that were previously infeasible offering tremendous new opportunites to do short, efficient organic syntheses in academia and industry
  • Includes supplementary material: sn.pub/extras

Part of the book series: Topics in Organometallic Chemistry (TOPORGAN, volume 3)

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Table of contents (10 chapters)

  1. Front Matter

    Pages I-VII
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  2. A General Survey and Recent Advances in the Activation of Unreactive Chemical Bonds by Metal Complexes

    • Robert A. Gossage, Gerard van Koten
    Pages 1-8

  3. Activation of C-H Bonds: Stoichiometric Reactions

    • William D. Jones
    Pages 9-46

  4. Activation of C-H Bonds: Catalytic Reactions

    • Fumitoshi Kakiuchi, Shinji Murai
    Pages 47-79

  5. Catalytic Activation of Methane and Ethane by Metal Compounds

    • Ayusman Sen
    Pages 81-95

  6. Cleavage of Carbon—Carbon Single Bonds by Transition Metals

    • Masahiro Murakami, Yoshihiko Ito
    Pages 97-129

  7. Activation of Si—Si Bonds by Transition-Metal Complexes

    • Michinori Suginome, Yoshihiko Ito
    Pages 131-159

  8. Activation of C-O Bonds: Stoichiometric and Catalytic Reactions

    • Yong-Shou Lin, Akio Yamamoto
    Pages 161-192

  9. Activation of Otherwise Unreactive C-Cl Bonds

    • Vladimir V. Grushin, Howard Alper
    Pages 193-226

  10. Activation of the N-N Triple Bond in Molecular Nitrogen: Toward its Chemical Transformation into Organo-Nitrogen Compounds

    • Masanobu Hidai, Yasushi Mizobe
    Pages 227-241

  11. Metal Reagents for Activation and Functionalization of Carbon-Fluorine Bonds

    • Thomas G. Richmond
    Pages 243-269

  12. Back Matter

    Pages 271-272
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Keywords

About this book

In the last few years a large repetoire of methods for the activation of unreactive organic functionalities and for their use in organic synthesis has been developed. In this volume, areas ranging from the activation of C-H bonds to the chemical transformation of dinitrogen are authoritatively discussed by leading experts in the field. To activate means to be able to cleave otherwise inert chemical bonds. The cleavage and formation of chemical bonds is fundamental to organic synthesis; these new activation methodologies make hitherto infeasible reactions extremely easy and create new opportunities for innovative organic transformations, for both industry and academia. This is the first book that provides a thorough and timely coverage of both inorganic and organic synthetic aspects of bond activation, thus giving a broad overview of the field and allowing both inorganic and organic chemists ready access to the methodologies involved.

Editors and Affiliations

  • Department of Applied Chemistry Faculty of Engineering, Osaka University, Osaka

    Shinji Murai

Bibliographic Information

  • Book Title: Activation of Unreactive Bonds and Organic Synthesis

  • Editors: Shinji Murai, H. Alper, R. A. Gossage, V. V. Grushin, M. Hidai, Y. Ito, W. D. Jones, F. Kakiuchi, G. Koten, Y.-S. Lin, Y. Mizobe, S. Murai, M. Murakami, T. G. Richmond, A. Sen, M. Suginome, … A. Yamamoto

  • Series Title: Topics in Organometallic Chemistry

  • DOI: https://doi.org/10.1007/3-540-68525-1

  • Publisher: Springer Berlin, Heidelberg

  • eBook Packages: Springer Book Archive

  • Copyright Information: Springer-Verlag Berlin Heidelberg 1999

  • Hardcover ISBN: 978-3-540-64862-8Published: 16 April 1999

  • Softcover ISBN: 978-3-642-08436-2Published: 17 September 2011

  • eBook ISBN: 978-3-540-68525-8Published: 01 July 2003

  • Series ISSN: 1436-6002

  • Series E-ISSN: 1616-8534

  • Edition Number: 1

  • Number of Pages: IX, 267

  • Topics: Organic Chemistry, Inorganic Chemistry, Polymer Sciences

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