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Advanced Potentiometry

Potentiometric Titrations and Their Systematic Errors

  • Book
  • © 2009

Overview

Authors:
  1. Erzsébet Néher-Neumann

    1. Dept. Chemistry, Royal Institute of Technology (KTH), Stockholm, Sweden

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  • Provides a platform for the accurate interpretation of potentiometric titration data
  • The only recent monograph on the market to accurately present the calculation of stability constants and equilibrium processes without systematic errors

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Table of contents (8 chapters)

  1. Front Matter

    Pages i-xix
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  2. Introduction

    • Erzsébet Néher Neumann
    Pages 1-16

  3. Emf Cells with Mixtures of Strong Electrolytes and Liquid Junctions of the Type AY | AY + HY + BYz(B)

    • Erzsébet Néher Neumann
    Pages 17-46

  4. Determination of the Ionic Molar Conductivities in Mixtures of the Strong Electrolytes HClO4 + NaClO4 + Cd(ClO4)2

    • Erzsébet Néher Neumann
    Pages 47-76

  5. Studies on Emf Cells Where Complex Formation Takes Place Using Liquid Junctions of the Type AY | AY + HY + BYz(B) + AyL and − log10 [H+] ≤ 7

    • Erzsébet Néher Neumann
    Pages 77-173

  6. Estimation of the Total Potential Anomalies and the Determination of the Equilibrium Constants in Emf Cells Where Every Kind of Complex Can Be Present

    • Erzsébet Néher Neumann
    Pages 175-179

  7. On Emf Titrations Proposed for the Determination of Some Interaction Coefficients [1]

    • Erzsébet Néher Neumann
    Pages 181-197

  8. Emf Titrations Proposed for the Determination of Certain Transport Numbers [1]

    • Erzsébet Néher Neumann
    Pages 199-211

  9. Studies on Emf Cells Where Strong Complexes Are Formed Using Liquid Junctions of the Type AY | AY + BYz(B) + HY + AyL AT [Y–] = C M, Constant, and – log10 [H+] ≥ 7 [1]

    • Erzsébet Néher Neumann
    Pages 213-233

  10. Back Matter

    Pages 235-239
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Keywords

About this book

"Advanced Potentiometry" details the accurate calculation of potentiometric titrations. Additional terms such as the ideal diffusion potential together with the contribution of activity factors furnish calculated stability constants which do not include systematic errors and thus present a complete and correct description of equilibrium processes. Moreover, serious systematic errors resulting from the recent use of curve-fitting computer programs are highlighted later in the text.

"Advanced Potentiometry" can advantageously be used by lecturers, researchers, PhD graduates and undergraduate students working in the fields of Solution Chemistry, Physical Chemistry, Inorganic Chemistry and Analytical Chemistry and Environmental Research.

Authors and Affiliations

  • Dept. Chemistry, Royal Institute of Technology (KTH), Stockholm, Sweden

    Erzsébet Néher-Neumann

Bibliographic Information

  • Book Title: Advanced Potentiometry

  • Book Subtitle: Potentiometric Titrations and Their Systematic Errors

  • Authors: Erzsébet Néher-Neumann

  • DOI: https://doi.org/10.1007/978-1-4020-9525-2

  • Publisher: Springer Dordrecht

  • eBook Packages: Chemistry and Materials Science, Chemistry and Material Science (R0)

  • Copyright Information: Springer Science+Business Media B.V. 2009

  • Hardcover ISBN: 978-1-4020-9524-5Published: 04 May 2009

  • Softcover ISBN: 978-90-481-8148-3Published: 19 October 2010

  • eBook ISBN: 978-1-4020-9525-2Published: 14 March 2010

  • Edition Number: 1

  • Number of Pages: XX, 350

  • Number of Illustrations: 37 b/w illustrations

  • Topics: Physical Chemistry, Analytical Chemistry

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