Fluid Transport in Nanoporous Materials

1. Front Matter

   Pages I-XII

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2. NATO-ASI FLUID TRANSPORT IN NANOPOROUS MATERIALS COURSE .a student’s perspective and explanations from a veteran

   • T. Q. GARDNER, D. M. RUTHVEN

   Pages 1-7

3. TRANSPORT IN MICROPOROUS SOLIDS: AN HISTORICAL PERPECTIVE Part I: Fundamental Principles and Sorption Kinetics

   • D. M. RUTHVEN

   Pages 9-39

4. MEASUREMENT OF DIFFUSION IN MACROMOLECULAR SYSTEMS: SOLUTE DIFFUSION IN POLYMERS SYSTEMS

   • R. L. LAURENCE

   Pages 41-68

5. THE ROLE OF DIFFUSION IN APPLICATIONS OF NOVEL NANOPOROUS MATERIALS AND IN NOVEL USES OF TRADITIONAL MATERIALS

   • L. SARKISOV, K.F. CZAPLEWSKI, R.Q. SNURR

   Pages 69-91

6. MODELING JUMP DIFFUSION IN ZEOLITES: I. PRINCIPLES AND METHODS

   • H. RAMANAN, S. M. AUERBACH

   Pages 93-125

7. ADSORPTION, THERMODYNAMICS AND MOLECULAR SIMULATIONS OF CYCLIC HYDROCARBONS IN SILICALITE-1 AND ALPO4-5 ZEOLITES

   • L. V. C. REES, L. SONG

   Pages 125-150

8. TRANSPORT IN MICROPOROUS SOLIDS Part II: Measurement of Micropore Diffusivities

   • D. M. RUTHVEN

   Pages 151-186

9. STRUCTURE-RELATED ANOMALOUS DIFFUSION IN ZEOLITES

   • S. VASENKOV, J. KÄRGER

   Pages 187-194

10. THE CONTRIBUTION OF SURFACE DIFFUSION TO TRANSPORT IN NANOPOROUS SOLIDS

    • W.C. CONNER

    Pages 195-210

11. THE MAXWELL-STEFAN FORMULATION OF DIFFUSION IN ZEOLITES

    • R. KRISHNA

    Pages 211-240

12. SENSITIVITY AND RESOLUTION IN MAGNETIC RESONANCE IMAGING OF DIFFUSIVE MATERIALS

    • R. H. ACOSTA, PETER BLÜMLER, H. W. SPIESS

    Pages 241-253

13. RESTRICTED DIFFUSION AND MOLECULAR EXCHANGE PROCESSES IN POROUS MEDIA AS STUDIED BY PULSED FIELD GRADIENT NMR

    • V. SKIRDA, A. FILIPPOV, A. SAGIDULLIN, A. MUTINA, R. ARCHIPOV, G. PIMENOV

    Pages 255-278

14. VIBRATIONAL SPECTROSCOPY TO MONITOR SYNTHESIS, ADSORPTION AND DIFFUSION IN MICRO- AND MESOPOROUS METAL PHOSPHATES

    • S. KENANE, C. S. VASAM, P. P. KNOPS-GERRITS

    Pages 279-298

15. NITROGEN – OXYGEN DIFFUSION IN ZEOLITES STUDIED BY DRIFT

    • V.B. KAZANSKY

    Pages 299-314

16. 129Xe NMR FOR DIFFUSION OF HYDROCARBONS IN ZEOLITES AND 1H NMR IMAGING FOR COMPETITIVE DIFFUSION OF BINARY MIXTURES OF HYDROCARBONS IN ZEOLITES

    • M.-A. SPRINGUEL-HUET

    Pages 315-332

17. DIFFUSION IN ZEOLITES MEASURED BY NEUTRON SCATTERING TECHNIQUES

    • H. JOBIC

    Pages 333-352

18. NMR IMAGING AS A TOOL FOR STUDYING MASS TRANSPORT IN POROUS MATERIALS

    • I.V. KOPTYUG, A.A. LYSOVA, A.V. MATVEEV, L.YU. ILYINA, R.Z. SAGDEEV, V.N. PARMON

    Pages 353-374

19. PFG NMR DIFFUSION STUDIES OF NANOPOROUS MATERIALS

    • S. VASENKOV, J. KÄRGER

    Pages 375-381

20. DIFFUSION OF CYCLIC HYDROCARBONS IN ZEOLITES BY FREQUENCY-RESPONSE AND MOLECULAR SIMULATION METHODS

    • L. V. C. REES, L. SONG

    Pages 383-413

The last several years have seen a dramatic increase in the synthesis of new nanoporous materials. The most promising include molecular sieves which are being developed as inorganic or polymeric systems with 0. 3-30nm in pore dimensions. These nanoporous solids have a broad spectrum of applications in chemical and biochemical processes. The unique applications of molecular sieves are based on their sorption and transport selectivity. Yet, the transport processes in nanoporous systems are not understood well. At the same time, the theoretical capabilities have increased exponentially catalyzed by increases in computational capabilities. The interactions between a diffusing species and the host solid are being studied with increasing details and realism. Further, in situ experimental techniques have been developed which give an understanding of the interactions between diffusing species and nanoporous solids that was not available even a few years ago. The time was ripe to bring together these areas of common interest and study to understand what is known and what has yet to be determined concerning transport in nanoporous solids. Molecular sieves are playing an increasing role in a broad range of industrial petrochemical and biological processes. These include shape-selective separations and catalysis as well as sensors and drug delivery. Molecular sieves are made from inorganic as well as organic solids, e. g. , polymers. They can be employed in packed beds, as membranes and as barrier materials. Initially, the applications of molecular sieves were dominated by the use of zeolites.

• Compound
• Phenoplaste
• Resol
• Styrol-Butadien
• polymer
• porous media
• thermodynamics

• Department of Chemical Engineering, University of Massachusetts, Amherst, U.S.A.

  Wm. Curtis Conner

• Laboratoire de Physique Quantique, ESPCI, Université Pierre et Marie Curie, Paris, France

  Jacques Fraissard

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