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Polyoxometalate Molecular Science

  • Book
  • © 2003

Overview

Editors:
  1. Juan J. Borrás-Almenar

    1. Institute of Molecular Science (ICMol), University of Valencia, Burjassot, Spain

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  2. Eugenio Coronado

    1. Institute of Molecular Science (ICMol), University of Valencia, Burjassot, Spain

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  3. Achim Müller

    1. Department of Chemistry, University of Bielefeld, Bielefeld, Germany

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  4. Michael Pope

    1. Department of Chemistry, Georgetown University, Washington, DC, USA

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Part of the book series: NATO Science Series II: Mathematics, Physics and Chemistry (NAII, volume 98)

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Table of contents (15 chapters)

  1. Front Matter

    Pages i-viii
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  2. Basic Concepts and Principles

    1. Front Matter

      Pages 1-1
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    2. Introduction to Polyoxometalate Chemistry

      • M. T. Pope
      Pages 3-31

    3. General Principles of The Synthesis of Polyoxometalates in Aqueous Solution

      • G. Hervé, A. Tézé, R. Contant
      Pages 33-54

    4. General Strategies for Non-Aqueous Polyoxometalate Synthesis

      • R. J. Errington
      Pages 55-78

    5. Complex Oxides as Molecular Materials: Structure and Bonding in High-Valent Early Transition Metal Compounds

      • J. C. Goloboy, W. G. Klemperer, T. A. Marquart, G. Westwood, O. M. Yaghi
      Pages 79-174

    6. Physical Methods in Studying Polyoxometalates: Extended HÜCkel Molecular Orbital Calculations and Spectroscopic Properties

      • L. R Kazansky
      Pages 175-209

    7. Time-Resolved Electron Spin Resonance Spectroscopy of Photoredox Reactions of Polyoxometalates: Formation of Paramagnetic-Species Pair by Triplet Mechanism

      • T. Yamase
      Pages 211-229

  3. Relevant Types of POM Compounds

    1. Front Matter

      Pages 231-231
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    2. Functionalized Polyoxometalates

      • A. Proust
      Pages 233-252

    3. Sulfur-Containing Keggin Anions and Cyclic Polyoxothioanions

      • F. Sécheresse, E. Cadot
      Pages 253-271

    4. Magnetic Polyoxometalates

      • J. M. Clemente-Juan, E. Coronado, A. Gaitaariño
      Pages 273-295

    5. Combinatorially Linkable Metal-Oxide Based Units: Perspectives for Nano, Supramolecular, and Solid-State Chemistry

      • P. Kögerler, A. Müller
      Pages 297-323

  4. Materials and Applications

    1. Front Matter

      Pages 325-325
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    2. Applications of Polyoxometalates in Homogeneous Catalysis

      • R. Neumann
      Pages 327-349

    3. Heterogeneous Catalysis by Heteropoly Compounds

      • I. V. Kozhevnikov
      Pages 351-380

    4. Photochemistry and Photocatalysis by Polyoxometalates

      • E. Papaconstantinou, A. Hiskia
      Pages 381-416

    5. Hybrid Materials Based on Polyoxometalates with Solid State Properties

      • M. Clemente-Leon, E. Coronado, C. Giménez-Saiz, C.J. Gómez-Garca
      Pages 417-440

    6. Polyoxometalates in Tailored Supramolecular Architectures: From Structure to Function

      • D. G. Kurth, S. Liu, D. Volkmer
      Pages 441-466

  5. Back Matter

    Pages 467-474
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Keywords

About this book

Polyoxometalates (POMs) form a large, distinctive class of molecular inorganic compounds of unrivaled electronic versatility and structural variation, with impacts ranging from chemistry, catalysis, and materials science to biology, and medicine. This book covers the basic principles governing the structure, bonding and reactivity of these metal-oxygen cluster anions and the major developments in their molecular science.

The book comprises three sections. The first covers areas ranging from topological principles via synthesis and stability to reactivity in solution. It also focuses on the physical methods currently used to extract information on the molecular and electronic structures as well as the physical properties of these clusters. The second part reviews different types of POMs, focusing on those systems that currently impact other areas of interest, such as supramolecular chemistry, nanochemistry and molecular magnetism. The third section is devoted to POM-based materials and their applications and prospects in catalysis and materials science.

Editors and Affiliations

  • Institute of Molecular Science (ICMol), University of Valencia, Burjassot, Spain

    Juan J. Borrás-Almenar, Eugenio Coronado

  • Department of Chemistry, University of Bielefeld, Bielefeld, Germany

    Achim Müller

  • Department of Chemistry, Georgetown University, Washington, DC, USA

    Michael Pope

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